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Publikasjoner

NIBIOs ansatte publiserer flere hundre vitenskapelige artikler og forskningsrapporter hvert år. Her finner du referanser og lenker til publikasjoner og andre forsknings- og formidlingsaktiviteter. Samlingen oppdateres løpende med både nytt og historisk materiale. For mer informasjon om NIBIOs publikasjoner, besøk NIBIOs bibliotek.

2017

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Abstract

The water vapour sorption behaviour of a range of sheep wool types and alpaca was studied using dynamic vapour sorption. Sorption isotherms were interpreted using the polymer sorption model developed by Vrentas and Vrentas. Satisfactory fits were obtained for absorption and desorption isotherms with the adjustment of parameters outside the scope of what is allowed. This is possibly because the underlying Flory–Huggins approach does not take into account any clustering of sorbate within the polymer. Water clustering in the wool fibre, determined using the Zimm–Lundberg clustering function, starts above a fibre moisture content of approximately 20%. Sorption kinetics were analysed using the parallel exponential kinetics model, providing excellent fits and allowed for calculation of a fibre modulus at different relative humidities; the values were reasonable at the upper end of the hygroscopic range, but were overestimated at the lower end of the range.

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Abstract

The beneficial effects of consumption of berry fruits on a range of chronic diseases has been attributed (at least in part) to the presence of unique phytochemicals. Recently, we identified novel ursolic acid-based triterpenoid glycosides (TTPNs) in raspberry fruit and demonstrated their survival in human ileal fluids after feeding which confirmed their colon-availability in vivo. In this paper, in vitro digestion studies demonstrated that certain TTPNs were stable under gastrointestinal conditions and confirmed that these components may have been responsible for bioactivity noted in previous studies. Sequential extractions of raspberry puree, isolated seeds and unseeded puree showed that certain TTPN components (e.g. peak T1 m/z 679, and T2 m/z 1358) had different extractabilities in water/solvent mixes and were differentially associated with the seeds. Purified seed TTPNs (mainly T1 and T2) were shown to be anti-genotoxic in HT29 and CCD841 cell based in vitro colonocyte models. Further work confirmed that the seeds contained a wider range of TTPN-like components which were also differentially extractable in water/solvent mixes. This differential extractability could influence the TTPN composition and potential bioactivity of the extracts. There was considerable variation in total content of TTPNs (∼3-fold) and TTPN composition across 13 Rubus genotypes. Thus, TTPNs are likely to be present in raspberry juices and common extracts used for bioactivity studies and substantial variation exists in both content and composition due to genetics, tissue source or extraction conditions, which may all affect observed bioactivity.

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Abstract

Several mathematical models have been proposed for describing particle‐size distribution (PSD) data, but their characteristics and accuracy have not been investigated for the < 0.002, 0.002–0.05 and 0.05–2.0‐mm fractions separately. Therefore, the primary objective of this study was to examine the characteristics of various PSD models and to evaluate the accuracy of fitting to the entire PSD curve and to each of the three fractions separately. Thirty‐six PSD models were fitted to the experimental data of 160 soil samples from Iran. The beerkan estimation of soil transfer (BEST), Fredlund unimodal and bimodal, two‐ and three‐parameter Weibull, Rosin–Rammler and van Genuchten models provided the best fit to the experimental data of the three size fractions above, but with a different order of performance for the different fractions. For all textural fractions, the following models performed substantially less well than the other models: the offset‐non‐renormalized lognormal, simple lognormal, S‐curve, Schuhmann, Yang, Turcotte and Gompertz models. A comparison of the overall accuracy and simplicity of the models indicated that the BEST, two‐ and three‐parameter Weibull and Rosin–Rammler models provided the best fit to the experimental data for the entire curve, which is similar but does not correspond fully to the findings of a similar, earlier study. We found that the number of model parameters and the type of equation did not explain the models' fitting capabilities. We also found that the iterated function system (IFS) model performed better than the PSD models for all fractions. Comprehensive comparisons of PSD models will be of value to future model users, but it is important to note that such comparisons will remain dataset dependent. This is likely to continue until they are tested on a near‐infinite synthetic dataset that covers all possible data options.