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Publications

NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.

2013

2012

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Abstract

Sewage sludge application on soils represents an important potential source of silver nanoparticles (Ag NPs) to terrestrial ecosystems, and it is thus important to understand the fate of Ag NPs once in contact with soil components. Our aim was to compare the behavior of three different forms of silver, namely silver nitrate, citrate stabilized Ag NPs (5 nm) and uncoated Ag NPs (19 nm), in two soils with contrasting organic matter content, and to follow changes in binding strength over time. Soil samples were spiked with silver and left to age for 2 h, 2 days, 5 weeks or 10 weeks before they were submitted to sequential extraction. The ionic silver solution and the two Ag NP types were radiolabeled so that silver could be quantified by gamma spectrometry by measuring the 110mAg tracer in the different sequential extraction fractions. Different patterns of partitioning of silver were observed for the three forms of silver. All types of silver were more mobile in the mineral soil than in the soil rich in organic matter, although the fractionation patterns were very different for the three silver forms in both cases. Over 20% of citrate stabilized Ag NPs was extractible with water in both soils the first two days after spiking (compared to 1–3% for AgNO3 and uncoated Ag NPs), but the fraction decreased to trace levels thereafter. Regarding the 19 nm uncoated Ag NPs, 80% was not extractible at all, but contrary to AgNO3 and citrate stabilized Ag NPs, the bioaccessible fraction increased over time, and by day 70 was between 8 and 9 times greater than that seen in the other two treatments. This new and unexpected finding demonstrates that some Ag NPs can act as a continuous source of bioaccessible Ag, while AgNO3 is rapidly immobilized in soil.

Abstract

Norway has the world’s largest facility for testing and improving CO2 capture. The aim of carbon capture technology is to minimize greenhouse gas emissions through a reaction between amines and effluents from gas power plants. During the overall process of CO2 capture, amines and their transformation products might escape to the environment through emissions, leakage, and as solid waste. The two main groups of transformation products with the most potential to cause environmental harm have been identified as nitrosamines and nitramines, both of which are considered to be carcinogenic. Recent theoretical modelling as well as laboratory experiments have found nitramine compounds, 2-nitroaminoethanol (CAS: 74386-82-6) and dimethylnitramine (CAS: 4164-28-7) to be present. However, despite the likelihood of these compounds increasing in the environment, no environmental toxicity data for these compounds currently exist. The aim of this project was to provide an environmental risk assessment for the selected nitramine compounds taking into account the key trophic groups within freshwater, marine and terrestrial environments. The toxicity assessment was made using a suite of standardised bioassays for the measure of acute and chronic toxicity. In the soil environment, the most potent compound was 2-nitroaminoethanol, which impaired the reproduction of earthworms and the seedling emergence of sunflower and ryegrass. The opposite was found in the aquatic environment, with freshwater and marine species consistently more affected by dimethylnitramine. All the tested freshwater species were more sensitive to nitramines than marine species. The selected amines were not acutely toxic to aquatic and soil species, with EC50 in the mg/L range. Both nitramines increased the nitrogen and carbon transformation activity of soil microorganisms.

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Abstract

The selective serotonin reuptake inhibitors citalopram, sertraline, paroxetine, fluvoxamine and fluoxetine have been investigated in 10 l anaerobic lab-scale digesters with continuous stirring and mesophilic conditions at 37 °C to investigate whether they would be reduced or accumulated in sewage sludge depending on whether the bacteria present were able to use the SSRIs as a carbon source or not. The total SSRI concentration had a significant reduction in concentration during the anaerobic treatment process from theoretically 0.58 mg/l to 0.21 mg/l after 17 days. However, large differences in the reduction of the different compounds were found. Paroxetine and citalopram were found to be almost completely reduced at day 24 with reductions of 85% (citalopram) and 98% (paroxetine). Reductions of 32% (fluoxetine), 53% (fluvoxamine) and 38% (sertraline) indicate that these three compounds have a higher potential for accumulation. None metabolites of these compounds were found in the samples.