Publications
NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.
1995
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E.M. Løbersli Kåre Olav VennAbstract
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B. Mankovska K. Vrana Eiliv Steinnes Richard HorntvedtAbstract
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Praveen Sharma Anders LönneborgAbstract
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Torild Wickstrøm W. Lund R. ByeAbstract
The use of an alkaline sample solution for the determination of Se by the hydride generation technique offers the possibility of eliminating the interference from very high concentrations of Ni2, CO2, Fe3 and Cr3. In order to achieve this, complexing agents were employed to mask the interfering metal ions, After addition of the masking agent, the pH was adjusted to 12-13 with NaOH, and sodium tetrahydroborate was finally added in order to reduce selenite to selenide ions. The selenium hydride was generated by acidifying the solution with HCl in a flow system.Ethylenediaminetetraacetic acid and diethylenetriaminepentaacetic acid (DTPA) were found to be effective masking agents for Ni2 and Co2; the, interference from up to 8000 mg l(-1) of Ni2 or Co2 was eliminated. Tartrate was found to be a suitable masking agent for Fe3 and Cr3 UP to 5000 mg l(-1). Accurate results were obtained for the National Institute of Standards and Technology Standard Reference Materials 671 Nickel Oxide and 364 Low-alloy Steel, using combinations of DTPA and tartrate as masking agents. The detection limits were 0.1 mu g g(-1) for the Nickel Oxide and 0.3 mu g g(-1) for the Low-alloy Steel.
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Finn Roll-Hansen Helga Roll-HansenAbstract
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Alan A. Berryman Erik ChristiansenAbstract
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Finn H. Brække Bjørn HålandAbstract
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Torild Wickstrøm W. Lund R. ByeAbstract
Selenium was determined in nickel and steel alloys by hydride generation in combination with both atomic absorption spectrometry (AAS) (heated quartz tube) and inductively coupled plasma atomic emission spectrometry (ICP-AES).A serious depression of the Se signal was observed when AAS was used for the determination, although the interference from Ni, Co, Cr, Fe and Cu was effectively masked with complexing agents. The depression was reduced when ICP-AES was used instead of AAS, indicating a gaseous phase interference.The interference may be caused by the presence of hydrides of Sn and As. For the determination of Se in nickel alloys and low-alloy steels, the detection limit was lowered by a factor 1.5-3 when ICP-AES was used instead of AAS. Several standard reference materials (nickel alloys and low-alloy steels) were analysed for Se.