Publications
NIBIOs employees contribute to several hundred scientific articles and research reports every year. You can browse or search in our collection which contains references and links to these publications as well as other research and dissemination activities. The collection is continously updated with new and historical material.
2011
Authors
Marit Almvik Gunnhild Riise Randi Bolli Trond Børresen Agnethe Christiansen Sven R. Odenmarck Roger HoltenAbstract
The report presents the results from multi-year field studies of transport of the sulfonylurea herbicides tribenuron-methyl and amidosulfuron in a barley field in Norway. A method for sample preparation of water samples and LC-MS/MS analysis of 6 sulfonylurea herbicides tribenuron-methyl, amidosulfuron, metsulfuron-methyl, iodosulfuron-methyl, thifensulfuron-methyl, rimsulfuron) and 5 degradation products (INL5296, INA4098, AEF101630, IN70941, IN70942) is also described.
Abstract
No abstract has been registered
Authors
Ermias Deribe Bjørn Olav Rosseland Reidar Borgstrøm Brit Salbu Zinabu Gebremariam Elias Dadebo Hans Ragnar Norli Ole Martin EkloAbstract
No abstract has been registered
2010
Abstract
The gas chromatography mass spectrometry (GC-MS) deconvolution reporting software (DRS) from Agilent Technologies has been evaluated for its ability as a screening tool to detect a large number ofpesticides in incurred and fortified samples extracted with acetone/dichloromethane/light petroleum(Mini-Luke method). The detection of pesticides is based on fixed retention times using retention timelocking (RTL) and full scan mass spectral comparison with a partly customer built automated massspectral deconvolution and identification system (AMDIS) database. The GC-MS was equipped with a programmable temperature vaporising (PTV) injector system which enables more sample to be injected.In a blind study of 52 real samples a total number of 158 incurred pesticides were found. In addition to the 85 pesticides found by manual interpretation of GC-NPD/ECD chromatograms, the DRS revealed 73 morepesticides (+46%). The DRS system also shows its potential to discover pesticides which are normally notsearched for (EPN in long beans from Thailand). A spiking experiment was performed to blank matricesof apple, orange and lettuce with 177 different pesticides at concentration levels 0.02 and 0.1 mg/kg. The samples were analysed on GC-MS full scan and the AMDIS match factor was used as a mass spectralquality criterion. The threshold level of the AMDIS match factor was set at 20 to eliminate most of thefalse positives. AMDIS match factors from 20 up to 69 are regarded only as indication of a positive hit andmust be followed by manual interpretation. Pesticides giving AMDIS match factors at ≥70 are regarded as identified. To simplify and decrease the large amount of data generated at each concentration level,the AMDIS match factors ≥20 was averaged (mean AMF) for each pesticide including the commodities and their replicates. Among 177 different pesticides spiked at 0.02 and 0.1 mg/kg level, the percentage of mean AMF values ≥70 were 23% and 80%, respectively. For 531 individual detections of pesticides (177pesticides×3 replicates) giving AMDIS match factor 20 in apple, orange and lettuce, the detection rates at 0.02 mg/kg were 71%, 63% and 72%, respectively. For the 0.1 mg/kg level the detection rates were 89%,85% and 89%, respectively. In real samples some manual interpretation must be performed in addition. However, screening by GC-MS/DRS is about 5-10 times faster compared to screening with GC-NPD/ECDbecause the time used for manual interpretation is much shorter and there is no need for re-injection on GC-MS for the identification of suspect peaks found on GC-NPD/ECD.
2009
Authors
Ole Martin Eklo Marit Almvik Randi Bolli Trond Børresen Terje Haraldsen Lars Egil Haugen Roger Holten Gunnhild RiiseAbstract
This is a final report for the project Norwegian Scenarios II, part two, that has been performed in collaboration between Bioforsk Plant Health and Plant Protection, The Norwegian University of Life Sciences and the Norwegian Food Safety Authority. The aim of the project was to establish Norwegian scenarios for the models PRZM and MACRO and to use them for approval of new pesticides.
Abstract
Organochlorine pollutants in the major fish species (pike Esox lucius, perch Perca fluviatilis, and roach Rutilus rutilus) of Lake Arungen, Norway, were investigated after an extensive removal of large pike in 2004. The organochlorine pollutants detected in fish liver samples in 2005 were dichlorodiphenyltrichloroethane (DDTs), polychlorinated biphenyls (PCBs), hexachlorobenzene (HCB), and heptachlor epoxide (HCE). DDTs were the dominant among all analyzed OCs. Sigma PCB and HCB, detected in fish from two clearly distinct trophic levels (prey and predators), give an indication of biontagnification. All OC concentrations in female pike were significantly lower compared to males, which might be due to the removal of high concentrations of pollutants in roe during spawning. (c) 2009 Elsevier Ltd. All rights reserved.
Authors
Ole Martin Eklo Randi Bolli Jens Kværner Tore Sveistrup Frauke Hofmeister Eivind Solbakken Nicolas Jarvis Fredrik Stenemo Eirik Romstad Borghild Glorvigen Tor Anton GurenAbstract
No abstract has been registered
2008
Authors
Marit Almvik Gunnhild Riise Randi Bolli Agnethe Christiansen Sven R. Odenmarck Trond Børresen Cathrine Waage TveitAbstract
Although the sulfonylurea herbicides have been used for many years worldwide, few field studies have been performed and little is known about the occurrence, fate and transport of sulfonylureas in the field. This report presents results from the first controlled field and laboratory-studies on the fate of sulfonylurea herbicides in Norway and a method for sample preparation and LC-MS/MS analysis of sulfonylurea herbicides in water samples is also presented.
Authors
Marianne Stenrød J Perceval P Benoit Marit Almvik Randi Bolli Ole Martin Eklo Tore E. Sveistrup Jens KværnerAbstract
No abstract has been registered
Abstract
No abstract has been registered